Terminology
CotD

Character of the Day.
A CotD can also be a VotD, and often is.

VotD

Victim of the Day.
Someone who isn't necessarily the main focus of the ep but still gets targeted.

MotD Monster of the Day

If a character's name is in bold, it means multiple villains appear in that episode, but they're the main antagonist of the day.

Pluie Arc 01 MotD: Jama-P
VotD: Yuri and Hinagiku
02 MotD: Jama-P
03 CotD: Susumu Shindou and Mimiko
MotD: Jama-P
04 CotD: Ryuuzou and Elena Tanima
MotD: Jama-P		 Angel Lily awakens
05 CotD: Masahiro and Akemi Tamano, Akira Tamano
MotD: Jama-P		 Angel Daisy awakens
06 CotD: Shizuka
MotD: "Mega" Jama-P (1)
Ojama A/B (Cameo) (2)		 Jama-P is purified
Eyecatch BGM changes
07 CotD: Takashi Yamamoto and Yukiko Kawai
MotD: Omanma
08 VotD: Masami, Akiyo
MotD: Pajama		 Akiyo is never shown, only namedropped
09 CotD: Erika Miyagawa and Shinkichi Nakahata
MotD: Ohima
10 CotD: Judo Club, Beauty Club (3)
MotD: Sacchima
11 VotD: random students
MotD: Tanma (Chotto Tanma)
12 Aquelda
CotD: Reiko and Yamaguchi
MotD: Nanma		 Aquelda mini-arc
13 CotD: Shinichi Kaji
MotD: Daruma
Insert song: "Yume Miru Ai Tenshi"		 Aquelda mini-arc
14 Aquelda and Pluie Aquelda mini-arc
15 Nocturne
VotD: Yousuke Fuuma
MotD: Devil's Forest Tree (4)
Insert song: "Yume Miru Ai Tenshi"
16 Pluie and Raindevila
VotD: Yousuke Fuuma
MotD: Devil's Forest Tree
Sandra Arc 17 Noise, Blitz, Cloud
MotD: Thunder
Donna (Cameo)
Insert song: "Yume Miru Ai Tenshi"		 MotD is created by all three girls
18 Noise
CotD: Marilyn (5)
VotD: Yousuke Fuuma
MotD: wasp (6)
Insert songs: "Hitomi no Oku de Dakishimete", "Lucky & Happy", "21st Century Juliet"		 Saint Something Old is found
19
Blitz, Cloud
VotD: various classmates (7)
Insert song: "21st Century Juliet"		 Saint Something Blue is found
20 Cloud
CotD: Saori
Insert song: "21st Century Juliet"		 Saint Something Borrowed is found
21 CotD: Hitomi and Satomi
MotD: Sandra and Donna
22 Sandra (8)
CotD: Sonoko (5), unnamed male student
Igneous Arc 23 Igneous
CotD: Takuro Amano
MotD: Ranbo		 Takuro is also a key part of this whole arc btw
24 CotD: Natsumi (5)
MotD: Blackie
Insert song: "Zutto Aitakatta"
25 VotD: various girls
MotD: Tarashi
26 MotD: Ryuck Saint Something New is found
27 CotD: Reiko, kids (Taro)
MotD: Ukima		 Different character to ep 12's Reiko
28 CotD: Akiko Takeuchi, Jouji Tajima
MotD: Wolfen
Insert song: "Virgin Love"		 OP/ED/Eyecatches change
Church bell SFX are missing from final shot of OP
Igneous
->
Potamos		 29 Potamos
VotD: Reiko, kids		 Feat. "Wedding Takuro".
VotDs return from ep 27.
Missing SFX are added to OP theme
Bonus: human guise + punk Potamos
30 Igneous and Potamos
CotD: Takuro Amano
MotD: Pump		 MotD is Potamos' familiar
Potamos Arc 31 Potamos (Hiromi Kawanami)
VotD: several couples
MotD: Shimoshimo (multiple) -> Giant Shimoshimo		 Next episode preview BGM changes
32 CotD: Keiko, Manami, "Becca" (9)
MotD: Fusuma
Insert song: "Anata no Tenshi ni Naritai"
33 MotD: Potamos (multiple), butterfly (6)
(Shown in flashback) bat (6), various other generics
34 VotD: Yousuke Fuuma, Angel Lily, Angel Daisy
MotD: Rioma
35 VotD: Yousuke Fuuma
MotD: Tamatama (Onsen Tamatama)		 Angel Salvia is introduced
36 CotD: Scarlet Ohara
MotD: Brani
37 CotD: Angel Freesia (flashback)
MotD: Yukidaruma
(Shown in flashback) Freesia's murderer, various other generics
Insert song: "Wedding Wars -Ai wa Honoo-"		 Shizuka (CotD from ep 6) reappears
38 Potamos (Hiromi Kawanami)
MotD: Devil women (10)
Insert song: "Wedding Wars -Ai wa Honoo-"		 feat. the Igneous lookalike
Petora Arc 39 Petora (Gozuboro Iwamoto)
VotD: students, Yuri and Hinagiku
MotD: Hanma
Background devils at start of ep (Cameo) (11)
40 MotD: Sojiki
41 CotD: Takuro Amano
MotD: Yukinojo Hengema		 Viento first appears
42 Petora and Raindevila
VotD: Limone		 Viento appears
Viento Arc 43 Kachusha (12) and Raindevila
VotD: Yousuke Fuuma
44 MotD: Jamapon and Jamaccho -> Daijama Kachusha's there, too
45 Kachusha
CotD: Sakura Hanasaki (Celeste) (13)		 Past Love Angels
Uragano first appears (in a flashback)
46 Kachusha
47 Viento
Insert song: "Wedding Wars -Ai wa Honoo-"
Final Arc
(Raindevila)		 48 Jura, Hatred, Odos, Odio
49 Hatred, Odos, Odio
CotD: Uragano (spirit)
50 MotD: Phantoms (14)
51 Raindevila (Averse)
Insert song: "Wedding Wars -Ai wa Honoo-"
DX
(Deluxe)		 01 CotD: Kiyoshiro and Matsugoro
MotD: Spider Woman
Insert songs: "Kisetsu ga Kureta Jewel", "Merry Angel"		 MotD cameos on snack packages (Hanma, Ohima, Omanma)
02 Clark Oasis
CotD: John and Tom
Insert song: "Ichioku Ichi no Kiseki"
03 Hiromi Kawanami
CotD: Shishitaro and Torao
MotD: Golden Mask (15)
Insert song: "Monochrome"		 Featuring a cameo by... Usagi Tsukino?!? (top-left corner)
The Igneous lookalike also gets a cameo
04 Dr. Belphegor
CotD: Girl Student A/B/C, Boy Student A/B
MotD: "Neko Angels" (1), Chocolate Golem (16)
Insert song: "Koi wa Prism"		 Love Angels as kitties
Omake Angel Robo Wedding Peach Devil Mask/Pluie-R
MotD: Sacchima-X
The Love Angel Task Force's Final Battle King of Darkness and Pluie-RR (Pluie-P) (17)
MotD: Sacchima-XX (17), EVERYONE		 Angel Potamos appears
Virgin Love PV Various


(1) - Unofficial/fan nickname
(2) - Called "Jama-C" and "Jama-B" in the dub. They don't do anything, they just show up briefly in the first scene.
(3) - All club members are unnamed in the original; the dub names the leader "Beauty Betty".
(4) - Called "Tree Face" in the dub.
(5) - Doesn't really do anything, but I suppose she counts as a CotD
(6) - No official name
(7) - The names "Nobuyo", "Keiko", "Akiko", "Misako" and "Midori" are used in the ep, but it's not clarified who's who - except that the black-haired girl isn't any of them (her name isn't given), and it's implied Midori is the girl with plaits and glasses. No name is given for the boy, either.
(8) - Spelt "Sandora" on the volume 4 DVD box
(9) - Unnamed in the original, "Becca" is her dub name
(10) - Unnamed; the Japanese credits list them as "Woman Devil", the dub credits just collectively refer to the three as "Devil Woman"
(11) - Again, they don't do anything, but they're there
(12) - I think this should be "Katyusha", but "Kachusha" is how ADV spelt it, so...
(13) - Spelt "Celeso" on the volume 9 DVD box
(14) - Or "youma" in the original Japanese. This is a description, not a name as such.
(15) - Called "Gold Mask" in the credits
(16) - Unnamed in the original, "Chocolate Golem" is its dub name
(17) - Pronounced "Pluie Double R"/"Sacchima Double X", which is also how they're referred to in ADV's subtitles; the spellings I used here are how the original on-screen captions spell their names.

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